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It does block some of the same serotonin receptors that atypical antipsychotics block, such as 5-HT2A & 5-HT2C. The 2A one probably contributes some antipsychotic effects, but I don't know if mirtazapine is useful in psychosis. I'd assume it's not much good as a standalone antipsychotic, since drug companies like to push for any indication they can get and most probably found it unsuccessful.
 

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when does psychosis begin and when does SA end?

from what Ive heard its not helpful for genuine psychosis
 
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